Rheological response of entangled isotactic polypropylene melts in strong shear flows: Edge fracture, flow curves, and normal stresses

Extensional-flow-induced crystallization of isotactic polypropylene

A filament stretching extensional rheometer with a custom-built oven was used to investigate the effect of uniaxial flow on the crystallization of polypropylene. Prior to stretching, samples were heated to a temperature well above the melt temperature to erase their thermal and mechanical histories and the Janeschitz-Kriegl protocol was applied. The samples were stretched at extension rates in ...

Interfacial Stick-Slip Transition in Simple Shear of Entangled Melts

Nematic effects and strain coupling in entangled polymer melts under strong flow.

We use small-angle neutron scattering (SANS) to study labeled short chains with and without the influence of an entangled and highly stretched surrounding environment of longer chains. We find unequivocal evidence of nematic effects as the blend chains in steady state flow are stretched a factor ∼1.5 more from the presence of the long chain nematic field. In the pure melt we confirm that the no...

Causality in Strong Shear Flows

It is well known that the standard transport equations violate causality when gradients are large or when temporal variations are rapid. We derive a modified set of transport equations that satisfy causality. These equations are obtained from the underlying Boltzmann equation. We use a simple model for particle collisions which enables us to derive moment equations non-perturbatively, i.e. with...

Normal stresses in a shear flow of magnetorheological suspensions: viscoelastic versus Maxwell stresses